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khademinia, S., behzad, M. (2018). Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials. Journal of Nanoanalysis, (), -. doi: 10.22034/jna.2018.557281.1062
shahin khademinia; mahdi behzad. "Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials". Journal of Nanoanalysis, , , 2018, -. doi: 10.22034/jna.2018.557281.1062
khademinia, S., behzad, M. (2018). 'Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials', Journal of Nanoanalysis, (), pp. -. doi: 10.22034/jna.2018.557281.1062
khademinia, S., behzad, M. Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials. Journal of Nanoanalysis, 2018; (): -. doi: 10.22034/jna.2018.557281.1062

Low temperature hydrothermal synthesis, evaluation of band gap energies and catalytic performance for Biginelli reactions of Sr2-xAxNb2O7+δ (A=Eu3+ and Nd3+) (x = 0.01 and 0.05) nanomaterials

Articles in Press, Accepted Manuscript , Available Online from 01 March 2018  XML
Document Type: Original Research Paper
DOI: 10.22034/jna.2018.557281.1062
Authors
shahin khademinia email orcid ; mahdi behzad
Department of Inorganic Chemistry, Faculty of Chemistry, Semnan University, Semnan 35351-19111, Iran
Abstract
Nano powders Eu3+ and Nd3+ - doped Sr2Nb2O7 were prepared by a low temperature hydrothermal method at 120 ºC for 48 h followed by annealing at 400 ᵒC for 3 h among Sr(NO3)2 and Nb2O5, Eu2O3 and Nd2O3 raw materials at stoichiometric 1:1 Sr:Nb molar ratio. Characterization of the synthesized materials was performed by X-ray powder diffraction (XRPD) technique. FullProf program employing profile matching with constant scale factors was employed for structural analysis. The results showed that the patterns had a main Sr2Nb2O7 orthorhombic crystal structure with space group Cmc21. FESEM images showed that the synthesized nanomaterials had flower morphologies. Ultraviolet-visible spectra analysis showed that the synthesized Eu3+ and Nd3+ - doped Sr2Nb2O7 nanomaterials had light absorption in the ultraviolet light region. The direct optical band gap energies obtained from UV-Vis absorption spectra were 3.45, 3.50 and 3.80 eV for pure Sr2Nb2O7, S2 and S4, respectively. The catalytic activity of the obtained materials in the one-pot synthesis of the heterocyclic compounds 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) in Biginelli reaction is investigated. The optimized 0.03 g of the catalyst, 95 ºC reaction temperature, and 60 min reaction time are used for the other Biginelli reactions in this work.
Keywords
Sr2Nb2O7; Rietveld; Hydrothermal; Crystal Structure; Biginelli
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